General Chemistry/Useful Equations

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General Chemistry

Book Cover · Introduction ·  v d e 

Units: Matter · Atomic Structure · Bonding · Reactions · Solutions · Phases of Matter · Equilibria · Kinetics · Thermodynamics · The Elements

Appendices: Periodic Table · Units · Constants · Equations · Reduction Potentials · Elements and their Properties


Contents

[edit] General

Density \frac{mass}{volume}
Moles \frac{given~mass~(g)}{gram~formula~mass}
Percent Error \frac{measured - accepted}{accepted} \times 100%
Percent Composition (by mass) \frac{mass~of~part}{mass~of~whole} \times 100%
Molarity \frac{moles~of~solute}{moles~of~solution}

[edit] Atomic Structure

Symbol Meaning Symbol Meaning
E energy c speed of light
f frequency λ wavelength
Q charge r distance
ke Coulomb's constant
Energy of Wave E = hf
Wave Relation c = λf
Coulomb's Law F_e = k_e\frac{Q_1Q_2}{r^2}

[edit] Solutions, Liquids, and Gases

Symbol Meaning
P pressure
V volume
n number of moles
T temperature (in Kelvin)
Kf molal freezing point constant
Kb molal boiling point constant
χ mole fraction
m molality
M molarity


Rauolt's Law P_{solution} = P_{1} \chi_{1} + P_{2} \chi_{2} + \dots
Boiling Point Elevation \Delta T_{solution} = K_b \cdot m_{solute}
Freezing Point Depression \Delta T_{solution} = K_f \cdot m_{solute}
Ideal Gas Law PV = nRT
Combined Gas Law \frac{P_1 V_1}{n_1 T_1} = \frac{P_2 V_2}{n_2 T_2}
Titration MAVA = MBVB
Dilution M1V1 = M2V2

[edit] Equilibrium

Symbol Meaning
Keq equilibrium constant (general)
Kp pressure equilibrium constant
Kc concentration equilibrium constant
R gas law constant
T temperature (in Kelvin)
Δn moles of product – moles of reactant
pH pH = − log[H + ]
pOH pOH = − log[OH ]
(for water) pH + pOH = 14
Pressure/Concentration Kp = Kc(RT)Δn
Equilibrium,
for a reaction a\mathrm{A} + b\mathrm{B} \rightarrow c\mathrm{C} + d\mathrm{D}
K_{eq} = \frac{[\mathrm{C}]^c [\mathrm{D}]^d}{[\mathrm{A}]^a [\mathrm{B}]^b}

[edit] Thermochemistry

Symbol Meaning
q heat energy
m mass
C specific heat
T temperature (in Kelvin)
Heat Transfer q = mCΔT
Enthalpy ΔH = HproductsHreactants
Entropy ΔS = SproductsSreactants
Free Energy ΔG = ΔHTΔS