Battery Power/Lead Acid Batteries

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The lead-acid cell (usually part of a battery) also works on the principal of redox reactions. In its case the anode is a sheet of metallic lead immersed in H2SO4(aq). The lead oxidises according to the following equation:

Pb(s) + SO42-(aq) → PbSO4(s) + 2e-


The cathode is a sheet of lead dioxide, also immersed in H2SO4(aq), which is reduced:


PbO2(s) + 4H+(aq) + SO42-(aq) + 2e- → PbSO4(s) + 2H2O(l)


Thus the H2SO4(aq) is the electrolyte.