Materials Science

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Contents 1 Materials Processing 1.1 Single Crystal Methods 2 Materials Characterization 2.1 Microscopy 2.1.1 Optical Microscopy 3 Introduction 4 Ceramics 5 Liquid crystals 6 Thermochromics 7 Crystallography 8 Biocompatible material 9 Rutherford backscattering 10 Neutron diffraction 11 X-ray diffraction 12 Materials 13 Composite Materials 14 Nuclear reaction analysis 15 Concrete 16 Semiconductors 17 Analytical chemistry 18 References 18.1 Wikipedia histories

[edit] Materials Processing

In order to produce an article for any application out of a particular material there are several steps that may be required. The first step is usually to obtain the raw materials from our environment. This may involve discovering where these raw materials are located (often achieved with knowledge of geology) and developing processes to extract them from these locations (e.g. mining the ores, drilling for oil etc.). Otherwise, it may be possible to find sources of material suitable for recycling or reprocessing. Once these raw materials have been obtained they may need to undergo some initial processing to get them into a usable form. This may be some form of extractive metallurgy, chemical synthesis or some other chemical process. It may also be necessary to mix different raw materials to achieve a certain composition (e.g. alloying in metals) that is appropriate for or has been optimised the application. The application will usually require that the material be in a particular shape and a suitable shaping process or combination of process must be employed to achieve this. Often, it may be possible to produce a shape out of a material with any one of the many different shaping processes. However, there is usually one particular process that either results in particular benefits in terms of the properties of the material or the article that is produced or meets some other important criteria - such as low cost - that it is selected over the other options. Finally, it may be necessary or beneficial to process the article further, once it has been formed, in order to optimise the properties of the material.

Firstly, this chapter will present the various chemical processes that may be necessary to produce suitable materials from the raw materials in our environment. The different methods for shaping these materials will then be presented. Finally, the processes used to optimise the properties of the materials will be discussed.

[edit] Single Crystal Methods

Heat treatment is a process in which the material is heated and cooled to change the properties of the metal.

[edit] Materials Characterization

An important aspect of materials science is the characterisation of the materials that we use or study in order to learn more about them. Today, there is a vast array of scientific techniques available to the materials scientist that enables this characterisation. These techniques will be introduced and explained in this section.

[edit] Microscopy

Microscopy is a technique that, combined with other scientific techniques and chemical processes, allows the determination of both the composition and the structure of a material.

[edit] Optical Microscopy

Optical microscopes are formed of lenses that magnify and focus light. This light may have been transmitted through a material or reflected from a material's surface and can be used to ascertain a great deal of information about that material under evaluation. This can include whether the material is dense or contains porosity, what colour the material is, whether the material is composed of a single phase or contains multiple phases etc. A common practice performed in conjuction with optical microscopy is that of targetted and controlled chemical attack of the material using one of many chemical reagents available. For metallic materials, this technique combined with optical microscopy is know as optical metallography. The basis of this combined technique is that regions of different composition within a material as well as entirely different materials are affected differently when exposed to certain chemicals. These chemical effects are catalogued in various works and through an understanding of these effects and a systematic experimental process they can be used to determine material composition and structure. -->

[edit] Introduction

Materials science is an interdisciplinary field involving the properties of matter and its applications to various areas of science and engineering. It includes elements of applied physics and chemistry, as well as chemical, mechanical, civil and electrical engineering. With significant media attention to nanoscience and nanotechnology in the recent years, materials science has been propelled to the forefront at many universities, sometimes controversially.

The choice material of a given era is often its defining point: the stone age, Bronze Age, and steel age are examples. Materials science is one of the oldest forms of engineering and applied science. Modern materials science evolved directly from metallurgy, which itself evolved from mining. A major breakthrough in the understanding of materials occurred in the late 19th century, when Willard Gibbs demonstrated that thermodynamic properties relating to atomic structure in various phases are related to the physical properties of the material. Important elements of modern materials science are a product of the space race: the understanding and engineering of the metallic alloys and other materials that went into the construction of space vehicles was one of the enablers of space exploration. Materials science has driven, and been driven by, the development of revolutionary technologies such as plastics, semiconductors, and biomaterials.

Before the 1960s (and in some cases decades after), many materials science departments were named metallurgy departments, from a 19th and early 20th century emphasis on metals. The field has since broadened to include every class of materials, including: ceramics, polymers, semiconductors, magnetic materials, medical implant materials and biological materials.

In materials science, rather than haphazardly looking for and discovering materials and exploiting their properties, one instead aims to understand materials fundamentally so that new materials with the desired properties can be created.

The basis of all materials science involves relating the desired properties and relative performance of a material in a certain application to the structure of the atoms and phases in that material through characterization. The major determinants of the structure of a material and thus of its properties are its constituent chemical elements and the way in which it has been processed into its final form. These, taken together and related through the laws of thermodynamics, govern the material’s microstructure, and thus its properties.

An old adage in materials science says: "materials are like people; it is the defects that make them interesting". The manufacture of a perfect crystal of a material is physically impossible. Instead materials scientists manipulate the defects in crystalline materials such as precipitates, grain boundaries (Hall-Petch relationship), interstitial atoms, vacancies or substitutional atoms, creating a material with the desired properties.

Not all materials have a regular crystal structure. Polymers display varying degrees of crystallinity. Glasses, some ceramics, and many natural materials are amorphous, not possessing any long-range order in their atomic arrangements. These materials are much harder to engineer than crystalline materials. Polymers are a mixed case, and their study commonly combines elements of chemical and statistical thermodynamics to give thermodynamical, rather than mechanical descriptions of physical properties.

In addition to industrial interest, materials science has gradually developed into a field which provides tests for condensed matter or solid state theories. New physics emerges because of the diverse new material properties needed to be explained.

Radical materials advances can drive the creation of new products or even new industries, but stable industries also employ materials scientists to make incremental improvements and troubleshoot issues with currently used materials. Industrial applications of materials science include materials design, cost-benefit tradeoffs in industrial production of materials, processing techniques (casting, rolling, welding, ion implantation, crystal growth, thin-film deposition, sintering, glassblowing, etc.), and analytical techniques (characterization techniques such as electron microscopy, x-ray diffraction, calorimetry, nuclear microscopy (HEFIB), Rutherford backscattering, neutron diffraction, etc.).

Besides material characterisation, the material scientist/engineer also deals with the extraction of materials and their conversion into useful forms. Thus ingot casting, foundry techniques, blast furnace extraction, electrolytic extraction all are part of the required knowledge of a materials scientist/engineer. Often the presence, absence or variation of minute quantities of secondary elements and compounds in a bulk material will have a great impact on the final properties of the materials produced, for instance, steels are classified based on 1/10th and 1/100 weight percentages of the carbon and other alloying elements they contain. Thus, the extraction and purification techniques employed in the extraction of iron in the blast furnace will have an impact of the quality of steel that may be produced.

The overlap between physics and materials science has led to the offshoot field of materials physics, which is concerned with the physical properties of materials. The approach is generally more macroscopic and applied than in condensed matter physics. See the important publications in materials physics for more details on this field of study.

Alloys of metals is an important and significant part of materials science. Of all the metallic alloys in use today, the alloys of iron (steel, stainless steel, cast iron, tool steel, alloy steels) make up the largest proportion both by quantity and commercial value. Iron alloyed with various weight percentages of carbon gives low, mid and high carbon steels. For the steels, the hardness and tensile strength of the steel is directly related to the amount of carbon present, while increasing carbon levels lead to lower ductility and toughness. The addition of silicon and graphitization will produce cast irons (although some cast irons are made precisely with no graphitization). The addition of chromium, nickel and molybdenum to carbon steels (more than 10%) gives us stainless steels.

Other significant metallic alloys are those of aluminium, titanium, copper and magnesium. Copper alloys have been know for a long time (during the Bronze Age), while the alloys of the other three metals have been relatively recently developed, due to the chemical reactivity of these metals and the resultant difficulty in their extraction which wasn't accomplished (electrolytically) until recently. The alloys of aluminium, titanium and magnesium are also known and valued for their high strength to weight ratios and, in the case of magnesium, their ability to provide electromagnetic shielding. These materials find special applications where high strength-weight ratios are desired (aero-space industry).

Other than metals, polymers and ceramics are also an important part of material science. Polymers are the raw materials (the resins) used to make what we commonly call plastics. Plastics are actually the final product after many polymers and additives have been processed and shaped into a final shape and form. Polymers that have been around and are in current widespread use include polyethylene, polypropylene, polyvinyl-chloride, polystyrene, nylons, polyesters, acrylics, polyurethane, polycarbonates. Plastics are generally classified as "commodity", "specialty" and "engineering" plastics.

PVC is a commodity plastic, it is widely used, low cost and annual quantities are huge. It lends itself to an incredible array of applications, from faux leather to electrical insulation to cabling to packaging and vessels. Its fabrication and processing are simple and well-established. The versatility of PVC is due to the wide range of additives that it accepts. Additives in polymer science refers to the chemicals and compounds added to the polymer base to modify its physical and material properties.

Polycarbon would be normally considered an engineering plastic (other examples include PEEK, ABS). Engineering plastics are valued for their superior strengths and other special material properties. They are usually not used for disposable applications, unlike commodity plastics.

Specialty plastics are really the materials with unique characteristics, such as ultrahigh strength, electrical conductivity, electro-florescence, high thermal stability, etc.

It should be noted here that the dividing line between the various types of plastics is not based on material but rather their properties and applications. For instance, polypropylene (PP) is a cheap, slippery polymer commonly used to make disposable shopping bags and trash bags. It is commodity. But a variety of PP called Ultra-high Molecular Weight Polypropylene (UHMWPE) is an engineering plastic which is used extensively as the glide rails for industrial equipment.

Another application of material science in industry is the making of composite materials. Composite materials are structured materials composed of at least two different macroscopic phases. An example would be steel-reinforced concrete. Also, take a look at the plastic casing of your telly set, cell-phone: these plastic casings are usually a composite made up of a thermoplastic matrix such as acrylonitrile-butadiene-styrene (ABS)in which calcium carbonate chalk, talc, glass fibres or carbon fibres have been added (dispersants) for added strength, bulk, or electro-static dispersion.

[edit] Ceramics

The word ceramic is derived from the Greek word. The term covers inorganic non-metallic materials whose formation is due to the action of heat. Up until the 1950s or so, the most important of these were the traditional clays, made into pottery, bricks, tiles and are like, along with cements and glass. The traditional crafts are described in the article on pottery. A composite material of ceramic and metal is known as cermet. The word ceramic can be an adjective, and can also be used as a noun to refer to a ceramic material, or a product of ceramic manufacture. Ceramics is a singular noun referring to the art of making things out of ceramic materials.

Many ceramic materials are hard, porous and brittle. The study and development of ceramics includes methods to mitigate problems associated with these characteristics, and to accentuate the strengths of the materials as well as to investigate novel applications.

There are a number of ceramics that are semiconductors. Most of these are transition metal oxides that are II-VI semiconductors, such as zinc oxide.

While there is talk of making blue LEDs from zinc oxide, ceramicists are most interested in the electrical properties that show grain boundary effects.

One of the most widely used of these is the varistor. These are devices that exhibit the property that resistance drops sharply at a certain threshold voltage. Once the voltage across the device reaches the threshold, there is a breakdown of the electrical structure in the vicinity of the grain boundaries, which results in its electrical resistance dropping from several megohms down to a few hundred ohms. The major advantage of these is that they can dissipate a lot of energy, and they self reset — after the voltage across the device drops below the threshold, its resistance returns to being high.

This makes them ideal for surge-protection applications. As there is control over the threshold voltage and energy tolerance, they find use in all sorts of applications. The best demonstration of their ability can be found in electrical substations, where they are employed to protect the infrastructure from lightning strikes. They have rapid response, are low maintenance, and do not appreciably degrade from use, making them virtually ideal devices for this application.

Semiconducting ceramics are also employed as gas sensors. When various gases are passed over a polycrystalline ceramic, its electrical resistance changes. With tuning to the possible gas mixtures, very inexpensive devices can be produced.

Ceramic materials are usually ionic or covalently-bonded materials, and can be crystalline or amorphous. A material held together by either type of bond will tend to fracture before any plastic deformation takes place, which results in poor toughness in these materials. Additionally, because these materials tend to be porous, the pores and other microscopic imperfections act as stress concentrators, decreasing the toughness further, and reducing the tensile strength. These combine to give catastrophic failures, as opposed to the normally much more gentle failure modes of metals.

These materials do show plastic deformation. However, due to the rigid structure of the crystalline materials, there are very few available slip systems for dislocations to move, and so they deform very slowly. With the non-crystalline (glassy) materials, viscous flow is the dominant source of plastic deformation, and is also very slow. It is therefore neglected in many applications of ceramic materials.

Under some conditions, such as extremely low temperature, some ceramics exhibit superconductivity. The exact reason for this is not known, but there are two major families of superconducting ceramics.

Piezoelectricity, a link between electrical and mechanical response, is exhibited by a large number of ceramic materials, including the quartz used to measure time in watches and other electronics. Such devices use both properties of piezoelectrics, using electricity to produce a mechanical motion (powering the device) and then using this mechanical motion to produce electricity (generating a signal). The unit of time measured is the natural interval required for electricity to be converted into mechanical energy and back again.

The piezoelectric effect is generally stronger in materials that also exhibit pyroelectricity, and all pyroelectric materials are also piezoelectric. These materials can be used to inter convert between thermal, mechanical, and/or electrical energy; for instance, after synthesis in a furnace, a pyroelectric crystal allowed to cool under no applied stress generally builds up a static charge of thousands of volts. Such materials are used in motion sensors, where the tiny rise in temperature from a warm body entering the room is enough to produce a measurable voltage in the crystal.

In turn, pyroelectricity is seen most strongly in materials which also display the ferroelectric effect, in which a stable electric dipole can be oriented or reversed by applying an electrostatic field. Pyroelectricity is also a necessary consequence of ferroelectricity. This can be used to store information in ferroelectric capacitors, elements of ferroelectric RAM.

The most common such materials are lead zirconate titanate and barium titanate. Aside from the uses mentioned above, their strong piezoelectric response is exploited in the design of high-frequency loudspeakers, transducers for sonar, and actuators for atomic force and scanning tunneling microscopes.

Increases in temperature can cause grain boundaries to suddenly become insulating in some semiconducting ceramic materials, mostly mixtures of heavy metal titanates. The critical transition temperature can be adjusted over a wide range by variations in chemistry. In such materials, current will pass through the material until joule heating brings it to the transition temperature, at which point the circuit will be broken and current flow will cease. Such ceramics are used as self-controlled heating elements in, for example, the rear-window defrost circuits of automobiles.

At the transition temperature, the material's dielectric response becomes theoretically infinite. While a lack of temperature control would rule out any practical use of the material near its critical temperature, the dielectric effect remains exceptionally strong even at much higher temperatures. Titanates with critical temperatures far below room temperature have become synonymous with "ceramic" in the context of ceramic capacitors for just this reason.

Non-crystalline ceramics: Non-crystalline ceramics, being glasses, tend to be formed from melts. The glass is shaped when either fully molten, by casting, or when in a state of toffee-like viscosity, by methods such as blowing to a mold. If later heat-treatments cause this class to become partly crystalline, the resulting material is known as a glass-ceramic.

Crystalline ceramics: Crystalline ceramic materials are not amenable to a great range of processing. Methods for dealing with them tend to fall into one of two categories - either make the ceramic in the desired shape, by reaction in situ, or by "forming" powders into the desired shape, and then sintering to form a solid body. Ceramic forming techniques include shaping by hand (sometimes including a rotation process called "throwing"), slip casting, tape casting (used for making very thin ceramic capacitors, etc.), injection molding, dry pressing, and other variations. (See also Ceramic forming techniques. Details of these processes are described in the two books listed below.) A few methods use a hybrid between the two approaches.

In the early 1980s, Toyota researched production of an adiabatic ceramic engine which can run at a temperature of over 6000 °F (3300 °C). Ceramic engines do not require a cooling system and hence allow a major weight reduction and therefore greater fuel efficiency. Fuel efficiency of the engine is also higher at high temperature, as shown by Carnot's theorem. In a conventional metallic engine, much of the energy released from the fuel must be dissipated as waste heat in order to prevent a meltdown of the metallic parts.

Despite all of these desirable properties, such engines are not in production because the manufacturing of ceramic parts in the requisite precision and durability is difficult. Imperfection in the ceramic leads to cracks, which can lead to potentially dangerous equipment failure. Such engines are possible in laboratory settings, but mass-production is unfeasible with current technology.

Work is being done in developing ceramic parts for gas turbine engines. Currently, even blades made of advanced metal alloys used in the engines' hot section require cooling and careful limiting of operating temperatures. Turbine engines made with ceramics could operate more efficiently, giving aircraft greater range and payload for a set amount of fuel.

Ceramics are used in the manufacture of knives. The blade of the ceramic knife will stay sharp for much longer than that of a steel knife, although it is more brittle and can be snapped by dropping it on a hard surface.

Since the late 1990s, highly specialized ceramics, usually based on boron carbide, formed into plates and lined with Spectra, have been used in ballistic armored vests to repel large-caliber rifle fire. Such plates are known commonly as small-arms protective inserts (SAPI). Very similar technology is used to protect cockpits of some military airplanes, because of the low weight of the material.

Recently, there have been advances in ceramics which include bio-ceramics, such as dental implants and synthetic bones. Hydroxyapatite, the natural mineral component of bone, has been made synthetically from a number of biological and chemical sources and can be formed into ceramic materials. Orthopedic implants made from these materials bond readily to bone and other tissues in the body without rejection or inflammatory reactions. Because of this, they are of great interest for gene delivery and tissue engineering scaffolds. Most hydroxy apatite ceramics are very porous and lack mechanical strength and are used to coat metal orthopedic devices to aid in forming a bond to bone or as bone fillers. They are also used as fillers for orthopedic plastic screws to aid in reducing the inflammation and increase absorption of these plastic materials. Work is being done to make strong-fully dense nano crystalline hydroxapatite ceramic materials for orthopedic weight bearing devices, replacing foreign metal and plastic orthopedic materials with a synthetic natural bone mineral. Ultimately these ceramic materials may be used as bone replacements or with the incorporation of protein collagens, synthetic bones.

[edit] Liquid crystals

Liquid crystals are substances that exhibit a phase of matter that has properties between those of a conventional liquid, and those of a solid crystal. For instance, a liquid crystal (LC) may flow like a liquid, but have the molecules in the liquid arranged and/or oriented in a crystal-like way. There are many different types of LC phases, which can be distinguished based on their different optical properties (such as birefringence). When viewed under a microscope using a polarized light source, different liquid crystal phases will appear to have a distinct texture. Each "patch" in the texture corresponds to a domain where the LC molecules are oriented in a different direction. Within a domain, however, the molecules are well ordered. Liquid crystal materials may not always be in an LC phase (just as water is not always in the liquid phase: it may also be found in the solid or gas phase). Liquid crystals can be divided into thermotropic and lyotropic LCs. Thermotropic LCs exhibit a phase transition into the LC phase as temperature is changed, whereas lyotropic LCs exhibit phase transitions as a function of concentration of the mesogen in a solvent (typically water) as well as temperature.

Liquid crystals find wide use in liquid crystal displays, which rely on the optical properties of certain liquid crystalline molecules in the presence or absence of an electric field. In a typical device, a liquid crystal layer sits between two polarizers that are crossed (oriented at 90° to one another). The liquid crystal is chosen so that its relaxed phase is a twisted one. This twisted phase reorients light that has passed through the first polarizer, allowing it to be transmitted through the second polarizer and reflected back to the observer. The device thus appears clear. When an electric field is applied to the LC layer, all the mesogens align (and are no longer twisting). In this aligned state, the mesogens do not reorient light, so the light polarized at the first polarizer is absorbed at the second polarizer, and the entire device appears dark. In this way, the electric field can be used to make a pixel switch between clear or dark on command. Color LCD systems use the same technique, with color filters used to generate red, green, and blue pixels. Similar principles can be used to make other liquid crystal based optical devices.

Thermotropic chiral LCs whose pitch varies strongly with temperature can be used as crude thermometers, since the color of the material will change as the pitch is changed. Liquid crystal color transitions are used on many aquarium and pool thermometers. Other liquid crystal materials change color when stretched or stressed. Thus, liquid crystal sheets are often used in industry to look for hot spots, map heat flow, measure stress distribution patterns, and so on. Liquid crystal in fluid form is used to detect electrically generated hot spots for failure analysis in the semiconductor industry. Liquid crystal memory units with extensive capacity were used in Space Shuttle navigation equipment.

It is also worth noting that many common fluids are in fact liquid crystals. Soap, for instance, is a liquid crystal, and forms a variety of LC phases depending on its concentration in water.

[edit] Thermochromics

Thermochromism is the ability of substance to change colour due to a change in temperature. A mood ring is an excellent example of this, but it has many other uses. Thermochromism is one of several types of chromism.

The two basic approaches are based on liquid crystals and leuco dyes. Liquid crystals are used in precision applications, as their responses can be engineered to accurate temperatures, but their color range is limited by their principle of operation. Leuco dyes allow wider range of colors to be used, but their response temperatures are more difficult to set with accuracy.

Some liquid crystals are capable of displaying different colors at different temperatures. This change is dependent on selective reflection of certain wavelengths by the crystallic structure of the material, as it changes between the low-temperature crystallic phase, through anisotropic chiral or twisted nematic phase, to the high-temperature isotropic liquid phase. Only the nematic mesophase has thermochromic properties; this restricts the effective temperature range of the material.

The twisted nematic phase has the molecules oriented in layers with regularly changing orientation, which gives them periodic spacing. The light passing the crystal undergoes Bragg diffraction on these layers, and the wavelength with the greatest constructive interference is reflected back, which is perceived as a spectral color. As the crystal undergoes changes in temperature, thermal expansion occurs, resulting in change of spacing between the layers, and therefore in the reflected wavelength. The color of the thermochromic liquid crystal can therefore continuously range from black through the spectral colors to black again, depending on the temperature.

Some such materials are cholesteryl nonanoate or cyanobiphenyls.

Liquid crystals used in dyes and inks often come microencapsulated, in the form of suspension.

Liquid crystals are used in applications where the color change has to be accurately defined. They find applications in thermometers for room, refrigerator, aquarium, and medical use, and in indicators of level of propane in tanks.

Liquid crystals are difficult to work with and require specialized printing equipment. The material itself is also typically more expensive than alternative technologies. High temperatures, ultraviolet radiation, some chemicals and/or solvents have a negative impact on their lifespan.

Thermochromic paint is a relatively recent development in the area of color-changing pigments. It involves the use of liquid crystal or leuco dye technology. After absorbing a certain amount of light or heat, the crystallic or molecular structure of the pigment reversibly changes in such a way that it absorbs and emits light at a different wavelength than at lower temperatures. Thermochromic paints are seen quite often as a coating on coffee mugs, whereby once hot coffee is poured into the mugs, the thermochromic paint absorbs the heat and becomes colored or transparent, therefore changing the appearance of the mug.

[edit] Crystallography

Crystallography is the experimental science of determining the arrangement of atoms in solids. In older usage, it is the scientific study of crystals.

Before the development of X-ray diffraction crystallography (see below), the study of crystals was based on the geometry of the crystals. This involves measuring the angles of crystal faces relative to theoretical reference axes (crystallographic axes), and establishing the symmetry of the crystal in question. The former is carried out using a goniometer. The position in 3D space of each crystal face is plotted on a stereographic net, e.g. Wolff net or Lambert net. In fact, the pole to each face is plotted on the net. Each point is labelled with its Miller index. The final plot allows the symmetry of the crystal to be established.

Crystallographic methods now depend on the analysis of the diffraction patterns that emerge from a sample that is targeted by a beam of some type. The beam is not always electromagnetic radiation, even though X-rays are the most common choice. For some purposes electrons or neutrons are used, which is possible due to the wave properties of the particles. Crystallographers often explicitly state the type of illumination used when referring to a method, as with the terms X-ray diffraction, neutron diffraction and electron diffraction.

These three types of radiation interact with the specimen in different ways. X-rays interact with the spatial distribution of the valence electrons, while electrons are charged particles and therefore feel the total charge distribution of both the atomic nuclei and the surrounding electrons. Neutrons are scattered by the atomic nuclei through the strong nuclear forces, but in addition, the magnetic moment of neutrons is non-zero. They are therefore also scattered by magnetic fields. Because of these different forms of interaction, the three types of radiation are suitable for different crystallographic studies.

In several cases, an image of a microscopic object is generated by focusing the rays of the visible spectrum using a lens as in light microscopy. However, because the wavelength of visible light is long compared to atomic bond lengths and atoms themselves, it is necessary to use radiation with shorter wavelengths, such as X-rays. Employing shorter wavelengths implies abandoning microscopy and true imaging, however, because there exists no material from which a lens capable of focusing this type of radiation can be created. (That said, scientists have had some success focusing X-rays with microscopic Fresnel zone plates made from gold). Generally, in diffraction-based imaging, the only wavelengths used are those that are too short to be focused. This difficulty is the reason that crystals must be used.

Because of their highly ordered and repetitive structure, crystals are an ideal material for analyzing the structure of solids. To use X-ray diffraction as an example, a single X-ray photon diffracting off of one electron cloud will not generate a strong enough signal for the equipment to detect. However, many X-rays diffracting off many electron clouds in approximately the same relative position and orientation throughout the crystal will result in constructive interference and hence a detectable signal.

Crystallography is a tool that is often employed by materials scientists. In single crystals, the effects of the crystalline arrangement of atoms is often easy to see macroscopically, because the natural shapes of crystals reflect the atomic structure. In addition, physical properties are often controlled by crystalline defects. The understanding of crystal structures is an important prerequisite for understanding crystallographic defects. Mostly, materials do not occur in a syngle crystalline, but poly-crystalline form, such that the powder diffraction method plays a most important role in structural determination.

A number of other physical properties are linked to crystallography. For example, the minerals in clay form small, flat, platelike structures. Clay can be easily deformed because the platelike particles can slip along each other in the plane of the plates, yet remain strongly connected in the direction perpendicular to the plates. Such mechanisms can be studied by crystallographic texture measurements.

In another example, iron transforms from a body-centered cubic (bcc) structure to a face-centered cubic (fcc) structure called austenite when it is heated. The fcc structure is a close-packed structure, and the bcc structure is not, which explains why the volume of the iron decreases when this transformation occurs.

Crystallography is useful in phase identification: That is, when performing some kind of processing on a material, it is often desired to find out what compounds and what phases are present in the material. Each phase has a characteristic arrangement of atoms. Techniques like X-ray diffraction can be used to identify which patterns are present in the material, and thus which compounds are present (note: the determination of the "phases" within a material should not be confused with the more general problem of "phase determination," which refers to the phase of waves as they diffract from planes within a crystal, and which is a necessary step in the interpretation of complicated diffraction patterns).

Crystallography covers the enumeration of the symmetry patterns which can be formed by atoms in a crystal and for this reason has a relation to group theory and geometry. See symmetry group.

X-ray crystallography is the primary method for determining the molecular conformations of biological macromolecules, particularly protein and nucleic acids such as DNA and RNA. In fact, the double-helical structure of DNA was deduced from crystallographic data. The first crystal structure of a macromolecule was solved in 1958 (Kendrew, J.C. et al. (1958) A three-dimensional model of the myoglobin molecule obtained by X-ray analysis (Nature 181, 662–666). The Protein Data Bank (PDB) is a freely accessible repository for the structures of proteins and other biological macromolecules. RasMol can be used to visualize biological molecular structures.

Electron crystallography has been used to determine some protein structures, most notably membrane proteins and viral capsids.

[edit] Biocompatible material

In surgery, a biocompatible material (sometimes shortened to biomaterial) is a synthetic or natural material used to replace part of a living system or to function in intimate contact with living tissue. Biocompatible materials are intended to interface with biological systems to evaluate, treat, augment or replace any tissue, organ or function of the body. Biomaterials are usually non-viable, but may also be viable.

A biocompatible material is different from a biological material such as bone that is produced by a biological system. Artificial hips, vascular stents, artificial pacemakers, and catheters are all made from different biomaterials and comprise different medical devices.

Biomimetic materials are not made by living organisms but have compositions and properties similar to those made by living organisms. The calcium hydroxylapatite coating found on many artificial hips is used as a bone replacement that allows for easier attachment of the implant to the living bone.

Surface functionalization may provide a way to transform a bio-inert material into a biomimetic or even bio-active material by coupling of protein layers to the surface, or coating the surface with self-assembling peptide scaffolds to lend bioactivity and/or cell attachment 3-D matrix.

Different approaches to functionalization of biomaterials exist. Plasma processing has been successfully applied to chemically inert materials like polymers or silicon to graft various functional groups to the surface of the implant. Polyanhydrides are polymers successfully used as a drug delivery materials.

[edit] Rutherford backscattering

Rutherford backscattering (or RBS, for Rutherford Backscattering Spectrometry) is an analytical technique in materials science. It is named for Ernest Rutherford who in 1911 first explained Geiger and Marsden's experimental results for alpha particle scattering from a very thin gold foil in a backward direction by using the Coulomb electrostatic force between the positively charged nucleus and the positively charged alpha particle. Rutherford first correctly described the atom as a tiny positive nucleus surrounded by negatively charged electrons (essentially the Bohr atom) on the basis of this experiment. This contradicted J.J. Thomson's "plum pudding model," the popularly accepted model of the atom at that time. Rutherford famously expressed his surprise at this experiment: "It was as though one fired a bullet at a piece of paper, and it bounced back at you!"

A high energy beam ( 2 to 4 MeV ) of low mass ions ( e.g. He++ ) is directed at a sample. A detector is placed such that particles which scatter from the sample at close to a 180 degree angle will be collected. The energy of these ions will depend on their incident energy and on the mass of the sample atom which they hit, because the amount of energy transferred to the sample atom in the collision depends on the ratio of masses between the ion and the sample atom. Thus, measuring the energy of scattered ions indicates the chemical composition of the sample.

Additionally, in the case that the incident ion doesn't hit any of the atoms near the surface of the sample, but instead hits an atom deeper in, the incident ion loses energy gradually as it passes through the solid, and again as it leaves the solid. This means that RBS can be used as a means to perform a depth profile of the composition of a sample. This is especially useful in analysis of thin-film materials. For example, films about half a micrometre in thickness can be profiled using a 2 MeV He beam, or films up to about 10 micrometres thick can be profiled with a 2 MeV H beam.

RBS is now a very widely used analytical technique, which has the great advantage that it is absolute, requiring no standards for quantification (since the probability of interaction - the cross-section - is given by the Coulomb potential). It is one of a family of techniques, collectively known as Ion beam analysis.

[edit] Neutron diffraction

Neutron diffraction is a crystallographic method for the determination of the atomic structure of a material. This is a form of elastic scattering where the neutrons exiting the experiment have more or less the same energy as the incident neutrons. The technique is similar to X-ray diffraction but the different type of radiation gives complementary information. A sample to be examined is placed in a beam of thermal or cold neutrons and the intensity pattern around the sample gives information of the structure of the material.

Neutrons are particles found in the atomic nucleus. In a nuclear reactor, neutrons can be set free when nuclei decay (fission, radioactivity). All quantum particles can exhibit wave phenomena we typically associate with light or sound. Diffraction is one of these phenomena; it occurs when waves encounter obstacles whose size is comparable with the wavelength. If the wavelength of a quantum particle is short enough, atoms or their nuclei can serve as diffraction obstacles. When neutrons from a reactor are slowed down and selected properly, their wavelength lies near one angstrom (0.1 nanometer), the typical separation between atoms in a solid material.

A neutron diffraction measurement requires a neutron source (e.g. a nuclear reactor or spallation source), a sample (the material to be studied), and a detector. At a research reactor other components such as crystal monochromators or filters may be needed to select the desired neutron wavelength. Some parts of the setup may also be movable. At a spallation source the time of flight technique is used to sort the energies of the incident neutrons, so no monochromator is needed, just a bunch of electronics. (Higher energy neutrons are faster - v. simple)

Neutrons interact with matter differently than x-rays. X-rays interact primarily with the electron cloud surrounding each atom. The contribution to the diffracted x-ray intensity is therefore larger for atoms with a large atomic number (Z) than it is for atoms with a small Z. On the other hand, neutrons interact directly with the nucleus of the atom, and the contribution to the diffracted intensity is different for each isotope; for example, regular hydrogen and deuterium contribute differently. It is also often the case that light (low Z) atoms contribute strongly to the diffracted intensity even in the presence of large Z atoms. Non-magnetic neutron diffraction is directly sensitive to the positions of the nuclei of the atoms. Although neutrons are uncharged, they carry a spin, and therefore interact with magnetic moments, including those arising from the electron cloud around an atom. Neutron diffraction can therefore reveal the microscopic magnetic structure of a material.

Neutron diffraction can be used to establish the structure of low atomic number materials like proteins and surfactants much more easily with lower flux than at a synchrotron radiation source. This is becuase some low atomic number materials have a higher cross section for neutron interaction than higher atomic weight materials.

The first neutron diffraction experiments were carried out in 1945 by Ernest O. Wollan using the Graphite Reactor at Oak Ridge. He was joined shortly thereafter by Clifford Shull, and together they established the basic principles of the technique, and applied it successfully to many different materials, addressing problems like the structure of ice and the microscopic arrangements of magnetic moments in materials. For this achievement Shull was awarded one half of the 1994 Nobel Prize in Physics. Wollan had passed away in the 1990's. (The other half of the 1994 Nobel Prize for Physics went to Bert Brockhouse for development of the inelastic scattering technique at the Chalk River facility of AECL. This also involved the invention of the triple axis spectrometer). Brockhouse and Shull jointly take the somewhat dubious distinction of the longest gap between the work being done (1945) and the Nobel Prize being awarded (1994).

One unusual application of elastic neutron scattering/diffraction is that the lattice constant of metals can be very accurately measured. Together with an accurately aligned micropositioner a map of the lattice constant through the metal can be derived. This can easily be converted to the stress field experienced by the material. This has been used to analyse stresses in aerospace and automotive components to give just two examples.

[edit] X-ray diffraction

X-ray scattering techniques are a family of non-destructive analytical techniques which reveal information about the crystallographic structure, chemical composition, and physical properties of materials and thin films. These techniques are based on observing the scattered intensity of an x-ray beam hitting a sample as a function of incident and scattered angle, polarization, and wavelength or energy.

[edit] Materials

Materials are physical substances used as inputs to production or manufacturing. Raw materials are first extracted or harvested from the earth and divided into a form that can be easily transported and stored, then processed to produce "semi-finished materials". These can be input into a new cycle of production and "finishing processes to create "finished materials", ready for distribution and consumption.

An example of a raw material is cotton, which can be processed into thread, and then processed into cloth, a semi-finished material. Sewing and cutting the fabric turns it into a garment, which is a finished material. Steelmaking is another example—raw materials are extracted, refined and processed into steel, a semi-finished material. Steel is then used as an input in many other industries to make finished products.

[edit] Composite Materials

Composite materials (or composites for short) are engineered materials made from two or more constituent materials with significantly different physical or chemical properties and which remain separate and distinct within the finished structure.

Composite materials (or composites for short) are engineering materials made from two or more constituent materials that remain separate and distinct on a macroscopic level while forming a single component. There are two categories of constituent materials: matrix and reinforcement. At least one portion of each type is required. The matrix material surrounds and supports the reinforcement materials by maintaining their relative positions. The reinforcements impart their special mechanical and physical properties to enhance the matrix properties. A synergism produces material properties unavailable from the individual constituent materials. Due to the wide variety of matrix and reinforcement materials available, the design potentials are incredible.

The most primitive composite materials comprised straw and mud in the form of bricks for building construction. The most advanced examples perform routinely on spacecraft in demanding environments. The most visible applications pave our roadways in the form of either steel and aggregate reinforced portland cement or asphalt concrete. Those composites closest to our personal hygiene form our shower stalls and bath tubs made of fiberglass. Solid surface, imitation granite and cultured marble sinks and countertops are widely used to enhance our living experiences.

There are the so-called natural composites like bone and wood. Both of these are constructed by the processes of nature and beyond the scope of this text. Engineered composite materials must be formed to shape. This involves strategically placing the reinforcements while manipulating the matrix properties to achieve a melding event at or near the beginning of the component life cycle. A variety of methods are used according to the end item design requirements. The principal factors impacting the methodology are the natures of the chosen matrix and reinforcement materials. Another important factor is the gross quantity of material to be produced. Large quantities can be used to justify high capital expenditures for rapid and automated manufacturing technology. Small production quantities are accommodated with lower capital expenditures but higher labor and tooling costs at a correspondingly slower rate.

Most commercially produced composites use a polymer matrix material often called a resin solution. There are many different polymers available depending upon the starting raw ingredients. There are several broad categories, each with numerous variations. The most common are known as polyester, vinyl ester, epoxy, phenolic, polyimide, polyamide, polypropylene, PEEK, and others. The reinforcement materials are often fibers but also commonly ground minerals.

The physical properties of composite materials are generally not isotropic in nature. For instance, the stiffness of a composite panel will often depend upon the directional orientation of the applied forces and/or moments. In contrast, an isotropic material has the same stiffness regardless of the directional orientation of the applied forces and/or moments. The relationship between forces/moments and strains/curvatures for an isotropic material can be described with the following material properties: Young's Modulus, the Shear Modulus and the Poisson's Ratio, in relatively simple mathematical relationships. For the anisotropic material, it requires the mathematics of a second order tensor and can require up to 21 material property constants. For the special case of orthogonal isotropy, there are three different material property constants for each of Young's Modulus, Shear Modulus and Poisson's Ratio for a total of 9 material property constants to describe the relationship between forces/moments and strains/curvatures.

Fiber Reinforced Composite Materials can be divided into two main categories normally referred to as short fiber reinforced materials and continuous fiber reinforced materials. Continuous reinforced materials will often constitute a layered or laminated structure.

Shocks, impact, loadings or repeated cyclic stresses can cause the laminate to separate at the interface between two layers, a condition known as delamination. Individual fibers can separate from the matrix e.g. fiber pull-out.

[edit] Nuclear reaction analysis

Nuclear reaction analysis (NRA) is a nuclear method in materials science to obtain concentration vs. depth distributions for certain target chemical elements in a solid thin film.

If irradiated with select projectile nuclei at kinetic energies Ekin these target elements can undergo a nuclear reaction under resonance conditions for a sharply defined resonance energy. The reaction product is usually a nucleus in an excited state which immediately decays, emitting ionizing radiation.

To obtain depth information the initial kinetic energy of the projectile nucleus (which has to exceed the resonance energy) and its stopping power (energy loss per distance travelled) in the sample has to be known. To contribute to the nuclear reaction the projectile nuclei have to slow down in the sample to reach the resonance energy. Thus each initial kinetic energy corresponds to a depth in the sample where the reaction occurs (the higher the energy, the deeper the reaction).

[edit] Concrete

Concrete is a construction material that consists of cement, commonly Portland cement, aggregate (generally gravel and sand) and water.

Concrete solidifies and hardens after mixing and placement due to a chemical process known as hydration. The water reacts with the cement, which bonds the other components together and eventually creating a stone-like material. It is used to make pavements, architectural structures, foundations, motorways/roads, overpasses, parking structures, brick/block walls and footings for gates, fences and poles.

The Assyrians and Babylonians used clay as cement in their concrete. The Egyptians used lime and gypsum cement. In the Roman Empire, concrete made from quicklime, pozzolanic ash / pozzolana and an aggregate made from pumice was very similar to modern Portland cement concrete. In 1756, the British engineer John Smeaton pioneered the use of Portland cement in concrete, using pebbles and powdered brick as aggregate. In modern times the use of recycled materials as concrete ingredients is gaining popularity because of increasingly stringent environmental legislation. The most conspicuous of these is fly ash, a by product of coal fired power plants. This has a significant impact by reducing the amount of quarrying and landfill space required.

Portland cement is the most common type of cement in general usage. It is a basic ingredient of concrete, mortar and plaster. English engineer Joseph Aspdin patented Portland cement in 1824, and it was named after the limestone cliffs on the Isle of Portland in England because its color is similar to the stone quarried there. It consists of a mixture of oxides of calcium, silicon and aluminium. Portland cement and similar materials are made by heating limestone (a source of calcium) with clay, and grinding this product (called clinker) with a source of sulfate (most commonly gypsum). When mixed with water, the resulting powder will become a hydrated solid over time.

High temperature applications, such as masonry ovens and the like, generally require the use of a refractory cement; concretes based on Portland cement can be damaged or destroyed by elevated temperatures, but refractory concretes are better able to withstand such conditions.

The water and cement paste hardens and develops strength over time. In order to ensure an economical and practical solution, both fine and coarse aggregates are utilised to make up the bulk of the concrete mixture. Sand, natural gravel and crushed stone are mainly used for this purpose. However, it is increasingly common for recycled aggregates (from construction, demolition and excavation waste) to be used as partial replacements of natural aggregates, whilst a number of manufactured aggregates, including air-cooled blast furnace slag and bottom ash are also permitted.

Decorative stones such as quartzite, small river stones or crushed glass are sometimes added to the surface of concrete for a decorative "exposed aggregate" finish, popular among landscape designers.

Workability (or consistence, as it is known in Europe) is the ability of a fresh (plastic) concrete mix to fill the form / mould properly with the desired work (vibration) and without reducing the concrete's quality. Workability depends on water content, chemical admixtures, aggregate (shape and size distribution), cementitious content and age (level of hydration). Raising the water content or adding chemical admixtures will increase concrete workability. Excessive water will lead to increased bleeding (surface water) and / or segregation of aggregates (when the cement and aggregates start to separate), with the resulting concrete having reduced quality. The use of an aggregate with an undesirable gradation can result in a very harsh mix design with a very low slump, which cannot be readily made more workable by addition of reasonable amounts of water.

Workability can be measured by the "slump test", a simplistic measure of the plasticity of a fresh batch of concrete following the ASTM C 143 or EN 12350-2 test standards. Slump is normally measured by filling an "Abrams cone" with a sample from a fresh batch of concrete. The cone is placed with the wide end down onto a level, non-absorptive surface. When the cone is carefully lifted off, the enclosed material will slump a certain amount due to gravity. A relatively dry sample will slump very little, having a slump value of one or two inches (25 or 50 mm). A relatively wet concrete sample may slump as much as six or seven inches (150 to 175 mm).

Slump can be increased by adding chemical admixtures such as mid-range or high-range water reducing agents (super-plasticizers) without changing the water/cement ratio. It is bad practice to add extra water at the concrete mixer. High flow concrete, like self-consolidating concrete, is tested by other flow-measuring methods. One of these methods includes placing the cone on the narrow end and observing how the mix flows through the cone while it is gradually lifted.

Concrete has relatively high compressive strength, but significantly lower tensile strength (about 10% of the compressive strength). As a result, concrete always fails from tensile stresses — even when loaded in compression. The practical implication of this is that concrete elements subjected to tensile stresses must be reinforced. Concrete is most often constructed with the addition of steel or fiber reinforcement. The reinforcement can be by bars (rebar), mesh, or fibres, producing reinforced concrete. Concrete can also be prestressed (reducing tensile stress) using internal steel cables (tendons), allowing for beams or slabs with a longer span than is practical with reinforced concrete alone.

The ultimate strength of concrete is influenced by the water-cement ratio (w/c) [water-cementitious materials ratio (w/cm)], the design constituents, and the mixing, placement and curing methods employed. All things being equal, concrete with a lower water-cement (cementitious) ratio makes a stronger concrete than a higher ratio. The total quantity of cementitious materials (portland cement, slag cement, pozzolans) can affect strength, water demand, shrinkage, abrasion resistance and density. As concrete is a liquid which hydrates to a solid, plastic shrinkage cracks can occur soon after placement; but if the evaporation rate is high, they often can occur during finishing operations (for example in hot weather or a breezy day). Aggregate interlock and steel reinforcement in structural members often negates the effects of plastic shrinkage cracks, rendering them aesthetic in nature. Properly tooled control joints in slabs or saw cuts provide a plane of weakness so that cracks occur unseen inside the joint, making a nice aesthetic presentation. In very high strength concrete mixtures (greater than 10,000 psi), the strength of the aggregate can be a limiting factor to the ultimate compressive strength. In lean concretes (with a high water-cement ratio) the use of coarse aggregate with a round shape may reduce aggregate interlock.

Experimentation with various mix designs is generally done by specifying desired "workability" as defined by a given slump and a required 28 day compressive strength. The characteristics of the coarse and fine aggregates determine the water demand of the mix in order to achieve the desired workability. The 28 day compressive strength is obtained by determination of the correct amount of cementitious to achieve the required water-cement ratio. Only with very high strength concrete does the strength and shape of the coarse aggregate become critical in determining ultimate compressive strength.

The internal forces in certain shapes of structure, such as arches and vaults, are predominantly compressive forces, and therefore concrete is the preferred construction material for such structures.

Pervious concrete is sometimes specified by engineers and architects when porosity is required to allow some air movement or to facillitate the drainage and flow of water through structures. Pervious concrete is referred to as "no fines" concrete because it is manufactured by leaving out the sand or "fine aggregate". A pervious concrete mixture contains little or no sand (fines), creating a substantial void content. Using sufficient paste to coat and bind the aggregate particles together creates a system of highly permeable, interconnected voids that drains quickly. Typically, between 15% and 25% voids are achieved in the hardened concrete, and flow rates for water through pervious concrete are typically around 480 in./hr (0.34 cm/s, which is 5 gal/ft²/ min or 200 L/m²/min), although they can be much higher. Both the low mortar content and high porosity also reduce strength compared to conventional concrete mixtures, but sufficient strength for many applications is readily achieved.

Pervious concrete pavement is a unique and effective means to address important environmental issues and support sustainable growth. By capturing rainwater and allowing it to seep into the ground, porous concrete is instrumental in recharging groundwater, reducing stormwater runoff, and meeting US Environmental Protection Agency (EPA) stormwater regulations. The use of pervious concrete is among the Best Management Practices (BMPs) recommended by the EPA, and by other agencies and geotechnical engineers across the country, for the management of stormwater runoff on a regional and local basis. This pavement technology creates more efficient land use by eliminating the need for retention ponds, swales, and other stormwater management devices. In doing so, pervious concrete has the ability to lower overall project costs on a first-cost basis.

Engineers usually specify the required compressive strength of concrete, which is normally given as the 28 day compressive strength in megapascals (MPa) or pounds per square inch (psi). Twenty eight days is a long wait to determine if desired strengths are going to be obtained, so three-day and seven-day strengths can be useful to predict the ultimate 28-day compressive strength of the concrete. A 25% strength gain between 7 and 28 days is often observed with 100% OPC (ordinary Portland cement) mixtures, and up to 40% strength gain can be realized with the inclusion of pozzolans and supplementary cementitious materials (SCM's) such as fly ash and/or slag cement. As strength gain depends on the type of mixture, its constituents, the use of standard curing, proper testing and care of cylinders in transport, etc. it becomes imperative to equally rely on testing the fundamental properties of concrete in its fresh, plastic state.

Concrete is typically sampled while being placed, with testing protocols requiring that test samples be cured under laboratory conditions (standard cured). Additional samples may be field cured (non-standard) for the purpose of early 'stripping' strengths, that is, form removal, evaluation of curing, etc. but the standard cured cylinders comprise acceptance criteria. Concrete tests can measure the "plastic" (unhydrated) properties of concrete prior to, and during placement. As these properties affect the hardened compressive strength and durability of concrete (resistance to freeze-thaw) , the properties of slump (workability), temperature, density and age are monitored to ensure the production and placement of 'quality' concrete. Tests are performed per ASTM International or CSA (Canadian Standards Association) and European methods and practices. Technicians performing concrete tests MUST be certified. Structural design and material properties are often specified in accordance with ACI International code (www.concrete.org) under the "prescription" or "performance" purchasing options per ASTM C94 (www.astm.org).

Compressive strength tests are conducted using an instrumented hydraulic ram to compress a cylindrical or cubic sample to failure. Tensile strength tests are conducted either by three-point bending of a prismatic beam specimen or by compression along the sides of a cylindrical specimen.

When structures made of concrete are to be demolished, concrete recycling is a common method of disposing of the rubble. Concrete debris was once routinely shipped to landfills for disposal, but recycling has a number of benefits that have made it a more attractive option in this age of greater environmental awareness, more environmental laws, and the desire to keep construction costs down.

Pieces of concrete collected from demolition sites are put through a crushing machine, often along with asphalt, bricks, and rocks. Crushing facilities accept only uncontaminated concrete, which must be free of trash, wood, paper and other such materials. Metals such as rebar are accepted, since they can be removed with magnets and other sorting devices and melted down for recycling elsewhere. The remaining aggregate chunks are sorted by size. Larger chunks may go through the crusher again. Smaller pieces of concrete are used as gravel for new construction projects. Aggregate base gravel is laid down as the lowest layer in a road, with fresh concrete or asphalt placed over it. Crushed recycled concrete can sometimes be used as the dry aggregate for brand new concrete if it is free of contaminants, though the use of recycled concrete limits the strength, and is not allowed in many jurisdictions.

Recycling concrete provides environmental benefits, as recycling concrete saves landfill space and using recycled concrete as aggregate reduces the need for gravel mining.

Bacteria themselves do not have noticeable effect on concrete. However, anaerobic bacteria in eg. sewage tend to produce hydrogen sulfide, which is then oxidized by aerobic bacteria present in biofilm on the concrete surface above the water level to sulfuric acid which dissolves the carbonates in the cured cement and causes strength loss. Concrete floors laying on ground containing pyrite are also at risk. Using limestone as the aggregate makes the concrete more resistant to acids, and the sewage may be pretreated by ways increasing pH or oxidizing or precipitating the sulphides in order to inhibit the activity of sulphide utilizing bacteria.

Concrete exposed to sea water is susceptible to its corrosive effects. The effects are more pronounced above the tidal zone than where the concrete is permanently submerged. In the submerged zone, magnesium and hydrogen carbonate ions precipitate about 30 micrometers thick layer of brucite on which a slower deposition of calcium carbonate as aragonite occurs. These layers somewhat protect the concrete from other processes, which include attack by magnesium, chloride and sulfate ions and carbonation. Above the water surface, mechanical damage may occur by erosion by waves themselves or sand and gravel they carry, and by crystallization of salts from water soaking into the concrete pores and then drying up. Pozzolanic cements and cements using more than 60% of slag as aggregate are more resistant to sea water than pure portland cement.

When some aggregates containing dolomite are used, a dedolomitization reaction occurs where the magnesium carbonate compound reacts with hydroxyl ions and yields magnesium hydroxide and a carbonate ion. The resulting expansion may cause destruction of the material. Other reactions and recrystallizations, e.g. hydration of clay minerals in some aggregates, may lead to destructive expansion as well.

[edit] Semiconductors

A semiconductor is a solid whose electrical conductivity can be controlled over a wide range, either permanently or dynamically. Semiconductors are tremendously important technologically and economically. Silicon is the most commercially important semiconductor, though dozens of others are important as well.

Semiconductor devices, electronic components made of semiconductor materials, are essential in modern electrical devices, from computers to cellular phones to digital audio players.

Semiconductors are very similar to insulators. The two categories of solids differ primarily in that insulators have larger band gaps — energies that electrons must acquire to be free to flow. In semiconductors at room temperature, just as in insulators, very few electrons gain enough thermal energy to leap the band gap, which is necessary for conduction. For this reason, pure semiconductors and insulators, in the absence of applied fields, have roughly similar electrical properties. The smaller bandgaps of semiconductors, however, allow for many other means besides temperature to control their electrical properties.

Semiconductors' intrinsic electrical properties are very often permanently modified by introducing impurities, in a process known as doping. Usually it is reasonable to approximate that each impurity atom adds one electron or one "hole" (a concept to be discussed later) that may flow freely. Upon the addition of a sufficiently large proportion of dopants, semiconductors conduct electricity nearly as well as metals. Depending on kind of the impurity, a region of semiconductor can have more electrons or holes, and then it is called N-type or P-type semiconductor, respectively. Junctions between regions of N- and P-type semiconductors have built-in electric fields, which cause electrons and holes to escape from them, and are critical to semiconductor device operation. Also, a density difference of impurities produces in the region small electric field which is used to accelerate non-equilibrium electrons or holes in it.

In addition to permanent modification through doping, the electrical properties of semiconductors are often dynamically modified by applying electric fields. The ability to control conductivity in small and well-defined regions of semiconductor material, both statically through doping and dynamically through the application of electric fields, has led to the development of a broad range of semiconductor devices, like transistors. Semiconductor devices with dynamically controlled conductivity are the building blocks of integrated circuits, like the microprocessor. These "active" semiconductor devices are combined with simpler passive components, such as semiconductor capacitors and resistors, to produce a variety of electronic devices.

In certain semiconductors, when electrons fall from the conduction band to the valence band (the energy levels above and below the band gap), they often emit light. This photoemission process underlies the light-emitting diode (LED) and the semiconductor laser, both of which are very important commercially. Conversely, semiconductor absorption of light in photodetectors excites electrons from the valence band to the conduction band, facilitating reception of fiber optic communications, and providing the basis for energy from solar cells.

Semiconductors may be elemental materials such as silicon and germanium, or compound semiconductors such as gallium arsenide and indium phosphide, or alloys such as silicon germanium or aluminium gallium arsenide.

Like other solids, the electrons in semiconductors can have energies only within certain bands between the energy of the ground state, corresponding to electrons tightly bound to the atomic nuclei of the material, and the free electron energy, which is the energy required for an electron to escape entirely from the material. The energy bands each correspond to a large number of discrete quantum states of the electrons, and most of the states with low energy are full, up to a particular band called the valence band. Semiconductors and insulators are distinguished from metals because the valence band in the former materials is very nearly full under normal conditions.

The ease with which electrons in a semiconductor can be excited from the valence band to the conduction band depends on the band gap between the bands, and it is the size of this energy bandgap that serves as an arbitrary dividing line (roughly 4 eV) between semiconductors and insulators.

The electrons must move between states to conduct electric current, and so due to the Pauli exclusion principle full bands do not contribute to the electrical conductivity. However, as the temperature of a semiconductor rises above absolute zero, the states of the electrons are increasingly randomized, or smeared out, and some electrons are likely to be found in states of the conduction band, which is the band immediately above the valence band. The current-carrying electrons in the conduction band are known as "free electrons", although they are often simply called "electrons" if context allows this usage to be clear.

Electrons excited to the conduction band also leave behind electron holes, or unoccupied states in the valence band. Both the conduction band electrons and the valence band holes contribute to electrical conductivity. The holes themselves don't actually move, but a neighbouring electron can move to fill the hole, leaving a hole at the place it has just come from, and in this way the holes appear to move, and the holes behave as if they were actual positively charged particles.

One covalent bond between neighboring atoms in the solid is ten times stronger than the binding of the single electron to the atom, so freeing the electron does not imply to destroy the crystal structure.

The notion of holes, which was introduced for semiconductors, can also be applied to metals, where the Fermi level lies within the conduction band. With most metals the Hall effect reveals electrons to be the charge carriers, but some metals have a mostly filled conduction band, and the Hall effect reveals positive charge carriers, which are not the ion-cores, but holes. Contrast this to some conductors like solutions of salts, or plasma. In the case of a metal, only a small amount of energy is needed for the electrons to find other unoccupied states to move into, and hence for current to flow. Sometimes even in this case it may be said that a hole was left behind, to explain why the electron does not fall back to lower energies: It cannot find a hole. In the end in both materials electron-phonon scattering and defects are the dominant causes for resistance.

The energy distribution of the electrons determines which of the states are filled and which are empty. This distribution is described by Fermi-Dirac statistics. The distribution is characterized by the temperature of the electrons, and the Fermi energy or Fermi level. Under absolute zero conditions the Fermi energy can be thought of as the energy up to which available electron states are occupied. At higher temperatures, the Fermi energy is the energy at which the probability of a state being occupied has fallen to 0.5.

The dependence of the electron energy distribution on temperature also explains why the conductivity of a semiconductor has a strong temperature dependency, as a semiconductor operating at lower temperatures will have fewer available free electrons and holes able to do the work.

When ionizing radiation strikes a semiconductor, it may excite an electron out of its energy level and consequently leave a hole. This process is known as electron–hole pair generation. Electron-hole pairs are constantly generated from thermal energy as well, in the absence of any external energy source.

Electron-hole pairs are also apt to recombine. Conservation of energy demands that these recombination events, in which an electron loses an amount of energy larger than the band gap, be accompanied by the emission of thermal energy (in the form of phonons) or radiation (in the form of photons).

In the steady state, the generation and recombination of electron–hole pairs are in equipoise. The number of electron-hole pairs in the steady state at a given temperature is determined by quantum statistical mechanics. The precise quantum mechanical mechanisms of generation and recombination are governed by conservation of energy and conservation of momentum.

As probability that electrons and holes meet together is proportional to the product of their amounts, the product is in steady state nearly constant at a given temperature, providing that there is no significant electric field (which might "flush" carriers of both types, or move them from neighbour regions containing more of them to meet together) or externally driven pair generation. The product is a function of the temperature, as the probability of getting enough thermal energy to produce a pair increases with temperature, being approximately 1/exp(band gap / kT), where k is Boltzmann's constant and T is absolute temperature.

The probability of meeting is increased by carrier traps – impurities or dislocations which can trap an electron or hole and hold it until a pair is completed. Such carrier traps are sometimes purposely added to reduce the time needed to reach the steady state.

The property of semiconductors that makes them most useful for constructing electronic devices is that their conductivity may easily be modified by introducing impurities into their crystal lattice. The process of adding controlled impurities to a semiconductor is known as doping. The amount of impurity, or dopant, added to an intrinsic (pure) semiconductor varies its level of conductivity. Doped semiconductors are often referred to as extrinsic.

The materials chosen as suitable dopants depend on the atomic properties of both the dopant and the material to be doped. In general, dopants that produce the desired controlled changes are classified as either electron acceptors or donors. A donor atom that activates (that is, becomes incorporated into the crystal lattice) donates weakly-bound valence electrons to the material, creating excess negative charge carriers. These weakly-bound electrons can move about in the crystal lattice relatively freely and can facilitate conduction in the presence of an electric field. (The donor atoms introduce some states under, but very close to the conduction band edge. Electrons at these states can be easily excited to conduction band, becoming free electrons, at room temperature.) Conversely, an activated acceptor produces a hole. Semiconductors doped with donor impurities are called n-type, while those doped with acceptor impurities are known as p-type. The n and p type designations indicate which charge carrier acts as the material's majority carrier. The opposite carrier is called the minority carrier, which exists due to thermal excitation at a much lower concentration compared to the majority carrier.

For example, the pure semiconductor silicon has four valence electrons. In silicon, the most common dopants are IUPAC group 13 (commonly known as column III) and group 15 (commonly known as column V) elements. Group 13 elements all contain three valence electrons, causing them to function as acceptors when used to dope silicon. Group 15 elements have five valence electrons, which allows them to act as a donor. Therefore, a silicon crystal doped with boron creates a p-type semiconductor whereas one doped with phosphorus results in an n-type material.

Semiconductors with predictable, reliable electronic properties are necessary for mass production. The level of chemical purity needed is extremely high because the presence of impurities even in very small proportions can have large effects on the properties of the material. A high degree of crystalline perfection is also required, since faults in crystal structure (such as dislocations, twins, and stacking faults) interfere with the semiconducting properties of the material. Crystalline faults are a major cause of defective semiconductor devices. The larger the crystal, the more difficult it is to achieve the necessary perfection. Current mass production processes use crystal ingots between four and twelve inches (300 mm) in diameter which are grown as cylinders and sliced into wafers.

Because of the required level of chemical purity and the perfection of the crystal structure which are needed to make semiconductor devices, special methods have been developed to produce the initial semiconductor material. A technique for achieving high purity includes growing the crystal using the Czochralski process. An additional step that can be used to further increase purity is known as zone refining. In zone refining, part of a solid crystal is melted. The impurities tend to concentrate in the melted region, while the desired material recrystalizes leaving the solid material more pure and with fewer crystalline faults.

In manufacturing semiconductor devices involving heterojunctions between different semiconductor materials, the lattice constant, which is the length of the repeating element of the crystal structure, is important for determining the compatibility of materials.

[edit] Analytical chemistry

Analytical chemistry is the analysis of material samples to gain an understanding of their chemical composition, structure and function.

Analytical chemistry is a sub discipline of chemistry that has the broad mission of understanding the chemical nature of all matter. This differs from other sub disciplines of chemistry in that it is not intended to understand the physical basis for the observed chemistry as with physical chemistry and it is not intended to control or direct chemistry as is often the case in organic chemistry. Analytical chemistry generally does not attempt to use chemistry or understand its basis; however, these are common outgrowths of analytical chemistry research. Analytical chemistry has significant overlap with other branches of chemistry, especially those that are focused on a certain broad class of chemicals, such as organic chemistry, inorganic chemistry or biochemistry, as opposed to a particular way of understanding chemistry, such as theoretical chemistry. For example the field of bioanalytical chemistry is a growing area of analytical chemistry that addresses all analytical questions in biochemistry, (the chemistry of life). Analytical chemistry and experimental physical chemistry, however, have a unique relationship in that they are very unrelated in their mission but often share the most in common in the tools used in experiments.

Analytical chemistry is particularly concerned with the questions of "what chemicals are present, what are their characteristics and in what quantities are they present?" These questions are often involved in questions that are more dynamic such as what chemical reaction an enzyme catalyzes or how fast it does it, or even more dynamic such as what is the transition state of the reaction. Although analytical chemistry addresses these types of questions it stops after they are answered. The logical next steps of understanding what it means, how it fits into a larger system, how can this result be generalized into theory or how it can be used are not analytical chemistry. Since analytical chemistry is based on firm experimental evidence and limits itself to some fairly simple questions to the general public it is most closely associated with hard numbers such as how much lead is in drinking water.

Modern analytical chemistry is dominated by instrumental analysis. There are so many different types of instruments today that it can seem like a confusing array of acronyms rather than a unified field of study. Many analytical chemists focus on a single type of instrument. Academics tend to either focus on new applications and discoveries or on new methods of analysis. The discovery of a chemical present in blood that increases the risk of cancer would be a discovery that an analytical chemist might be involved in. An effort to develop a new method might involve the use of a tunable laser to increase the specificity and sensitivity of a spectrometric method. Many methods, once developed, are kept purposely static so that data can be compared over long periods of time. This is particularly true in industrial quality assurance (QA), forensic and environmental applications. Analytical chemistry plays an increasingly important role in the pharmaceutical industry where, aside from QA, it is used in discovery of new drug candidates and in clinical applications where understanding the interactions between the drug and the patient are critical.

Analytical methods rely on scrupulous attention to cleanliness, sample preparation, accuracy and precision.

Many practitioners will keep all their glassware in acid to prevent contamination, samples will be re-run many times over, and equipment will be washed in specially pure solvents.

A standard method for analysis of concentration involves the creation of a calibration curve.

If the concentration of element or compound in a sample is too high for the detection range of the technique, it can simply be diluted in a pure solvent. If the amount in the sample is below an instrument's range of measurement, the method of addition can be used. In this method a known quantity of the element or compound under study is added, and the difference between the concentration added, and the concentration observed is the amount actually in the sample.

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• Materials science
• Ceramics
• Liquid Crystals
• Thermochromic
• Crystallography
• Biocompatible material
• Rutherford_backscattering
• Neutron diffraction
• X-ray diffraction
• Material
• Composite material
• Nuclear reaction analysis
• Concrete
• Semiconductors
• Analytical chemistry