Chemical Sciences: A Manual for CSIR-UGC National Eligibility Test for Lectureship and JRF/Distonic ion

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Distonic ions are chemical species that contain both a radical and an ionic site on different atoms of the same molecule.[1][2] They were first discovered in the gas phase by Michael L. Gross.[3] In recent years there has been a tremendous effort to identify new distonic species, characterize their reactivity, and measure their stability.[4][5][6]

References[edit]

  1. International Union of Pure and Applied Chemistry. "distonic radical cation". Compendium of Chemical Terminology Internet edition.
  2. Stirk, Krista M. (1992). "Ion-molecule reactions of distonic radical cations". Chemical Reviews 92: 1649. doi:10.1021/cr00015a008. 
  3. Holman, R. (1986). "Mass spectrometry for investigations of gas-phase radical cation chemistry the two step cycloaddition of the benzene radical cation and 1,3-butadiene". Tetrahedron 42: 6235. doi:10.1016/S0040-4020(01)88085-6. 
  4. Tomazela DM, Sabino AA, Sparrapan R, Gozzo FC, Eberlin MN (July 2006). "Distonoid ions". J. Am. Soc. Mass Spectrom. 17 (7): 1014–22. doi:10.1016/j.jasms.2006.03.008. http://linkinghub.elsevier.com/retrieve/pii/S1044-0305(06)00271-6. 
  5. Ibrahim Y, Mabrouki R, Meot-Ner M, El-Shall MS (February 2007). "Hydrogen bonding interactions of pyridine*+ with water: stepwise solvation of distonic cations". J Phys Chem A 111 (6): 1006–14. doi:10.1021/jp067390h. PMID 17286357. 
  6. Bouchoux G, Berruyer F, Hiberty PC, Wu W (2007). "Classical and distonic radical cations: a valence bond approach". Chemistry 13 (10): 2912–9. doi:10.1002/chem.200600985. PMID 17200931.